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Термодинамика, кинетика и расчеты металлургических процессов

2. CHEMICAL THERMODYNAMICS OF PYROMETALLURGICAL SYSTEMS AND PROCESSES

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2. CHEMICAL THERMODYNAMICS OF PYROMETALLURGICAL SYSTEMS AND PROCESSES
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Table of contents

2. CHEMICAL THERMODYNAMICS OF PYROMETALLURGICAL SYSTEMS AND PROCESSES-
2.1. ON THE DRIVING FORCE AND EQUILIBRIUM CONDITIONS FOR CHEMICAL REACTIONS AND SYSTEMS
2.1.1. Gibbs energy change in an isothermal chemical reaction
2.1.2. Refractory-steel interaction as an example for chemical system undergoing chemical reaction
2.1.3. Manual calculation of (complex) reaction equilibria in a gaseous mixture
2.1.4. Substitutional and competing chemical reactions
2.2. GAS AND SIMPLE GAS-SOLID SYSTEMS
2.2.1. Composition and properties of gas systems most common in metallurgical processes
2.3. METALLIC SOLUTIONS
2.3.1. Standard states and composition co-ordinates for mixtures and solution phases
2.4. INTERACTIONS IN METAL-GAS-SYSTEMS
2.4.1. Copper-sulphur and copper-sulphur-oxygen systems
2.4.2. Vacuum refining of blister copper
2.4.3. Decarburisation of chromium hot metal
2.5. OXID SOLUTIONS AND METALLURGICAL SLAGS
2.5.1. Model of perfect ionic solution (Temkin's model)
2.5.2. Using the model of a perfect ionic solution in calculation of metallurgical ssag component activities
2.5.3. Polymeric models of silica melts (Masson's model)
2.5.4. The model of regular ionic solution (Kozheurov's model)
2.5.5. Thermodynamic model of slag as a phase, which has a shared electron System (Ponomarenko's vjdel)
2.5.6. Optical basicity
2.5.7. Electrochemical measurements and calculations in oxide solutions
2.6. EXAMPLES OF REACTIONS BETWEEN METAL AND SLAG
2.6.1. Deoxidation of steel
2.6.2. Desulphurisation
2.6.3. Dephosphorisation of steel
2.7. DISTRIBUTION OF ELEMENTS BETWEEN MOLTEN COPPER OR COPPER MATTE AND SLAG
2.7.1. Copper-slag distribution
2.7.2. Distribution of elements between copper matte and slag
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